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2011, 08, 25-27
硝酸法生产磷酸过程中稀土的浸出研究
基金项目(Foundation): 国家科技支撑计划项目(2007BAB08B03)
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发布时间: 2011-08-15
出版时间: 2011-08-15
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摘要:

研究了采用硝酸法生产磷酸工艺中稀土的浸出情况。详细探讨了温度、硝酸浓度、时间、粒度、液固比等因素对磷精矿中稀土浸出率的影响。结果表明,浸出稀土的适宜工艺条件是:40%HNO3、60℃、液固比2.5、搅拌转速300 r/min、-0.038 mm占82%、浸出90 min。此条件下稀土浸出率与磷矿分解率均大于98%。

Abstract:

The leaching of rare earth(RE) in phosphate rock with nitric acid was studied.The effects of temperature,nitric acid concentration,time,particle size,and liquid-to-solid ratio on RE leaching rate were studied.The optimum conditions for RE leaching were 40% HNO3,60 ℃,liquid-to-solid ratio 2.5,agitation speed 300 r/min,-0.038 mm accounting for 82%,leaching time 90 min.Under the above conditions,the percentage of RE leaching rate and decomposition percentage of phosphate rock were both higher than 98%.

参考文献

[1]王明沁.波兰从磷灰石中提取稀土[J].稀土信息,1994(Z1):20.

[2]贾继奎.从磷灰石中提取稀土的工艺综述[J].有色金属与稀土应用,2001(4):25-29.

[3]Clur D A,Hansen K R N.Rare Earth Recovery From Phos-phogypsum:South African,ZA8005.318[P].1981.

[4]Jarosiski A,Kowalczyk J,Mazanek Cz.Development of thePolish Wasteless Technology of Apatite Phosphogypsum Uti-lization with Recovery of Rare Earths[J].J Alloys Comp,1993,200(1-2):147-150.

[5]龙志奇,王良士,黄小卫,等.湿法磷酸生产过程中控制稀土走向的研究[J].中国稀土学报,2008,26(3):307-312.

基本信息:

中图分类号:TF845

引用信息:

[1]汪胜东,蒋开喜,蒋训雄,等.硝酸法生产磷酸过程中稀土的浸出研究[J].有色金属(冶炼部分),2011(08):25-27.

基金信息:

国家科技支撑计划项目(2007BAB08B03)

发布时间:

2011-08-15

出版时间:

2011-08-15

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