| 455 | 7 | 55 |
| 下载次数 | 被引频次 | 阅读次数 |
广东某钽铌矿冶炼企业主要生产氟钽酸钾及氧化铌,年处理钽精矿130 t、铌钽铁合金220 t,年产生中和渣量约672 t,但由于原有工艺没有对酸溶渣、中和渣和废液进行分离,造成最终废物量大、放射性活度高和难处理等问题,厂区历史遗留中和渣约1万t。现该企业对生产工艺进行了改进,包括车间排放口处理废水、增加压滤机、总排放口优化、建设中和渣堆场和中和渣资源化利用等措施。经技术改造后,实现了渣液分离,产生的废水放射性物质达标排放,对历史遗留的中和渣进行资源化利用,减少中和渣填埋处置费用约3 000万元,获得了较好的经济效益、环境效益和社会效益。
Abstract:A Ta-Nb ore smelting enterprise in Guangdong province mainly produces potassium fluotantalate and niobium oxide It processes 130 t of tantalum concentrate and 220 t of ferrocolumbium tantalum as well as about 672 t of neutralization slag annually.However,due to the original processing without separation of acid-dissolved slag,neutralization slag and waste liquid,final waste volume is large and radioactive activity is high,which is difficult to treat and has left 10 kt of neutralization slag in factory.After technical improvement,including workshop wastewater treating,adding filter press,optimization of final discharge,construction of neutralization slag yard and recycling of neutralization slag,the slag and liquid separation has been realized,radioactivity reaches the standard and the historical neutralization slag has been recycled,which saves 30 million RMB cost of landfill and disposal of neutralization slag,and has obtained good economic,environmental and social benefits.
[1]张林.新时代钽铌产业发展[J].中国有色金属,2019(10):44-46.ZHANG L.Tantalum-niobium industry development in the new era[J].China Nonferrous Metals,2019(10):44-46.
[2]夏子通.钽铌冶炼辐射环境影响评价研究[D].北京:核工业北京地质研究院,2012.XIA Z T.Methodological study on radiological impact assessment of Ta-Nb metallurgy[D].Beijing:Beijing Research Institute of Uranium Geology,2012.
[3]黄膑.钽铌矿冶炼中的放射性污染及活度计算方法[J].能源研究与管理,2020(3):91-95.HUANG B.Radioactive pollution and activity calculation method in tantalum niobium ore smelting[J].Energy Research and Management,2020(3):91-95.
[4]陈柏迪,陈志东,邓飞,等.伴生放射性矿固体废物的放射性与重金属特性[J].核安全,2018,17(3):40-46.CHEN B D,CHEN Z D,DENG F,et al.The preliminary study about radioactivity and the heavy metal character in solid wastes of mines associated with radioactivity[J].Nuclear Safety,2018,17(3):40-46.
[5]刘永,陈逸凡,丁悦,等.伴生放射性矿放射性污染现状及其防治管理对策[J].南华大学学报(社会科学版),2020,21(4):1-5.LIU Y,CHEN Y F,DING Y,et al.The current situation of radioactive pollution of associated radioactive minerals and its countermeasures of prevention and management[J].Journal of University of South China(Social Science Edition),2020,21(4):1-5.
[6]薛福生.广东省伴生放射性固体废物处置分析[D].湖南衡阳:南华大学,2020.XUE F S,Analysis on disposal of associated radioactive solid waste in Guangdong province[D].Hengyang:University of South China,2020.
[7]陈志东,陈柏迪,邓飞,等.锆英砂类型伴生矿固体废物中核素与重金属释出的浸泡淋滤实验研究[J].核技术,2021,44(3):75-83.CHEN Z D,CHEN B D,DENG F,et al.Soaking and leaching experimental study on nuclides and heavy metals from zircon sand type associated radioactivity solid wastes[J].Nuclear Techniques,2021,44(3):75-83.
[8]薛梅.钽铌湿法冶金中的环境污染与治理措施[J].稀有金属与硬质合金,2005,33(4):55-59.XUE M.Environmental pollution and treatment of tantalum and niobium hydrometallurgy[J].Rare Metals and Cemented Carbides,2005,33(4):5 5-59.
[9]张浩.钽铌冶炼三废治理措施的探讨[J].有色金属科学与工程,2009,23(1):30-34.ZHANG H.On pollution treatment measures in Ta &Nb smelting[J].Nonferrous Metals Science and Engineering,2009,23(1):30-34.
[10]张平.石灰乳中和沉淀处理后的稀土水冶废水达标排放研究[J].中国辐射卫生,2008,17(2):210-211.ZHANG P.Study of the discharge standards of rare earth water smelting wastewater after neutralization and precipitation of lime cream[J].Chinese Journal of Radiological H ealth,2008,17(2):210-211.
[11]生态环境部核与辐射安全中心.核安全实务[M].北京:中国原子能出版社,2018:272.Nuclear and Radiation Safety Centre,Minstry of Ecology and Environment of the People's Republic of China.Nuclear Safety Practice[M].Beijing:China Atomic Energy Press,2018:272.
[12]张祺.谈硅酸盐水泥的生产工艺[J].中国化工贸易,2014,6(8):232.ZHANG Q.Discussion of the production technology about Portland cement[J].China Chemical Trade,2014,6(8):232.
[13]陈志东,李冠超,陈柏迪,等.广东省伴生放射性固体废物填埋处置关键技术研究与应用[R].广州:广东省环境辐射监测中心,2021.CHEN Z D,LI G C,CHEN B D,et al.The study and application of key technologies for landfill disposal of associated radioactive solid waste in Guangdong [R].Guangzhou:Guangdong Environmental Radiation Monitoring Center,2021.
基本信息:
中图分类号:X758
引用信息:
[1]陈志东.钽铌矿冶炼废渣的资源化利用[J].有色金属(冶炼部分),2021(11):122-127.
基金信息:
广东省生态环境厅项目(115-2019-XMZC-0009-30-0020)
2021-11-06
2021-11-06