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矿区环境的污染防治与生态修复是促进我国“十四五”生态文明建设的重要内容之一，促进风险管控与修复技术集成是治理矿山污染的必然趋势。回顾了近年来我国矿区污染的主要修复类与管控类技术，总结了风险管控模式下矿区污染场地一般修复思路，并在此基础上归纳概括了4种我国矿区的修复管控模式与实施案例，包括基于迁移转化规律、时空分布、场地利用方式及风险等级的矿区修复管控模式。以期为未来我国建立涵盖风险标准体系与技术体系的场地治理模式提供参考与支撑。
Abstract：Environmental pollution prevention and ecological restoration in mining areas is one of the important contents of promoting the construction of ecological civilization in China′s “14th Five-Year Plan”.The promotion in the integration of risk control and restoration technology is an inevitable trend in controlling mine pollution.The main remediation and control technologies of pollution in mining areas in China in recent years were reviewed.The general remediation ideas of contaminated sites in mining areas under the mode of risk management and control were summarized.On this basis, four kinds of the restoration and control modes and implementation cases of mining areas in China were summarized, including the restoration and control mode of mining areas based on the temporal and spatial distribution of pollutants, the law of migration and transformation, site utilization mode and risk level.This study can provide reference and support for the establishment of a site governance model covering risk standard system and technical system in China in the future.
[1] 中华人民共和国自然资源部.2021中国矿产资源报告[R].北京：地质出版社，2021.Ministry of Natural Resources of the People′s Republic of China.Chinamineral resources report[R].Beijing:Geological Publishing House,2021.
[2] 周连碧，王琼，杨越晴.典型金属矿区污染土壤生态修复研究与实践进展[J].有色金属(冶炼部分),2021(3):10-18.ZHOU L B,WANG Q,YANG Y Q.Progress in research and practice of ecological restoration of contaminated soil in typical metal mining areas[J].Nonferrous Metals (Extractive Metallurgy),2021(3):10-18.
[3] 李笑诺，陈卫平，吕斯丹.国内外污染场地风险管控技术体系与模式研究进展[J].土壤学报，2022,59(1):38-53.LI X N,CHEN W P,LYU S D.Advancement in researches on technical systems and modes for risk management and control of contaminated sites at home and aborad[J].Acta Pedologica Sinica,2022,59(1):38-53.
[4] 焦文涛，方引青，李绍华，等.美国污染地块风险管控的发展历程、演变特征及启示[J].环境工程学报，2021,15(5):1821-1830.JIAO W T,FANG Y Q,LI S H,et al.Risk management and control of contaminated sites in the United States:development process,evolution characteristics and enlightenment[J].Chinese Journal of Environmental Engineering,2021,15(5):1821-1830.
[5] 易诗懿，李笑诺，陈卫平.污染场地可持续风险管控区划研究进展[J].环境保护科学，2023,49(1):126-135.YI S Y,LI X N,CHEN W P.Research progress on contaminated site regionalization based on sustainable risk management[J].Environmental Protection Science,2023,49(1):126-135.
[6] 郝汉舟，陈同斌，靳孟贵，等.重金属污染土壤稳定/固化修复技术研究进展[J].应用生态学报，2011,22(3):816-824.HAO H Z,CHEN T B,JIN M G,et al.Recent advance in solidification/stabilization technology for the remediation of heavy metals-contaminated soil[J].Chinese Journal of Applied Ecology,2011,22(3):816-824.
[7] 桂娟，常海伟，和君强，等.中南有色金属冶炼场地与周边土壤重金属污染概况及稳定化修复技术研究进展[J].中国农学通报，2022,38(27):86-93.GUI J,CHANG H W,HE J Q,et al.Heavy metal pollution within and surrounding nonferrous metal smelting sites in Central-south China and stabilization remediation technology:a review[J].Chinese Agricultural Science Bulletin,2022,38(27):86-93.
[8] DONG Y B,ZENG W H,LIN H,et al.Preparation of Fe2O3-coated vermiculite composite by hydrophobic agglomeration and its application in As/Cd co-contaminated soil[J].Environmental Technology,2022,43(1):83-94.
[9] NONG X Y,ZHANG C L,CHEN H X,et al.Remediation of Cd,Pb and as Co-contaminated paddy soil by applying different amendments[J].Bulletin of Environmental Contamination and Toxicology,2020,105(2):283-290.
[10] 赵鑫娜，杨忠芳，余涛.矿区土壤重金属污染及修复技术研究进展[J].中国地质，2023,50(1):84-101.ZHAO X N,YANG Z F,YU T.Heavy mental pollution and research progress of remediation technology in mining area soil:a review[J].Geology in China,2023,50(1):84-101..
[11] ZHANG P Y,FAN J,XU X Y,et al.Contrasting effects of dry-wet and freeze-thaw aging on the immobilization of As in As-contaminated soils amended by zero-valent iron-embedded biochar[J].Journal of Hazardous Materials,2022,426:128123.DOI:10.1016/j.jhazmat.2021.128123.
[12] 徐雷，代惠萍，魏树和.淋洗剂在重金属污染土壤修复中的研究进展[J].中国环境科学，2021,41(11):5237-5244.XU L,DAI H P,WEI S H.Advances of washing agents in remediation of heavy metal contaminated soil[J].China Environmental Science,2021,41(11):5237-5244.
[13] 端爱玲，杨树俊，韩张雄，等.矿区土壤重金属污染化学修复及强化方法研究进展[J].矿产综合利用，2022(6):104-109.DUAN A L,YANG S J,HAN Z X,et al.Research progress on chemical remediation and strengthening methods of heavy metal contaminated soil in mining areas[J].Multipurpose Utilization of Mineral Resources,2022(6):104-109.
[14] YU X A,ZHOU T,ZHAO J,et al.Remediation of a metal-contaminated soil by chemical washing and repeated phytoextraction:a field experiment[J].International Journal of Phytoremediation,2021,23(6):577-584.
[15] 孟晓飞，郑国砥，陈同斌，等.两种油菜配施水溶性壳聚糖修复典型铅污染农田土壤[J].环境科学，2022,43(5):2741-2750.MENG X F,ZHENG G D,CHEN T B,et al.Phytoremediation efficiency of two cultivars of Brassica napus L.under water-soluble chitosan treatment in typical Pb-contaminated farmland soils[J].Environmental Science,2022,43(5):2741-2750.
[16] 艾姣，刘俊梅，闫明.重金属污染影响下的矿区土壤生物修复技术[J].能源与环保，2022,44(9):40-45.AI J,LIU J M,YAN M.Bioremediation technology of soil in mining area under influence of heavy metal pollution[J].China Energy and Environmental Protection,2022,44(9):40-45.
[17] ZHU Q,HU Z Q,RUAN M Y.Characteristics of sulfate-reducing bacteria and organic bactericides and their potential to mitigate pollution caused by coal gangue acidification[J].Environmental Technology & Innovation,2020,20:101142.DOI:10.1016/j.eti.2020.101142.
[18] NGUYEN V,CHOI W,YU J,et al.Microbial oxidation of antimonite and arsenite by bacteria isolated from antimony-contaminated soils[J].International Journal of Hydrogen Energy,2017,42(45):27832-27842.
[19] YIN T T,LIN H,DONG Y B,et al.A novel constructed carbonate-mineralized functional bacterial consortium for high-efficiency cadmium biomineralization[J].Journal of Hazardous Materials,2021,401:123269.DOI:10.1016/j.jhazmat.2020.123269.
[20] CHEN J X,CAO Y,YAN X J,et al.Novel PvACR3;2 and PvACR3;3 genes from arsenic-hyperaccumulator Pteris vittata and their roles in manipulating plant arsenic accumulation[J].Journal of Hazardous Materials,2021,415:125647.DOI:10.1016/j.jhazmat.2021.125647.
[21] LIU H,ZHAO H X,WU L H,et al.Heavy metal ATPase 3 (HMA3) confers cadmium hypertolerance on the cadmium/zinc hyperaccumulator Sedum plumbizincicola[J].New Phytologist,2017,215(2):687-698.
[22] 秦芙蓉，张仕颖，夏运生，等.来利山锡尾矿区优势植物调查与生态修复潜力分析[J].环境科学，2021,42(8):3963-3970.QIN F R,ZHANG S Y,XIA Y S,et al.Investigation of dominant plants and analysis of ecological restoration potential in Lailishan tin tailings[J].Environmental Science,2021,42(8):3963-3970.
[23] YAN Y X,YANG J,WAN X M,et al.Temporal and spatial differentiation characteristics of soil arsenic during the remediation process of Pteris vittata L.and Citrus reticulata Blanco intercropping[J].Science of the Total Environment,2022,812:152475.https://doi.org/10.1016/j.scitotenv.2021.152475.
[24] YAN Y X,YANG J,GUO Y,et al.Potential evaluation of different intercropping remediation modes based on remediation efficiency and economic benefits:a case study of arsenic-contaminated soil[J].International Journal of Phytoremediation,2022,24(1):25-33.
[25] 罗侠，刘燕，巩银萍，等.尾矿区污染现状与生物修复研究[J].环境生态学，2022,4(7):78-82.LUO X,LIU Y,GONG Y P,et al.Pollution and biological restoration of tailings[J].Environmental Ecology,2022,4(7):78-82.
[26] 杨黎萌.废弃露天矿山生态修复技术的实践应用[J].世界有色金属，2022(13):202-204.YANG L M.Practice application of ecological repair technology of abandoned open mining mine[J].World Nonferrous Metals,2022(13):202-204.
[27] 吴慧，吴程龙，张仕颖，等.施用有机-无机改良剂对锡尾矿化学属性的影响[J].生态环境学报，2021,30(11):2244-2250.WU H,WU C L,ZHANG S Y,et al.Effects of applying organic-inorganic modifiers on the chemical properties of tin tailings[J].Ecology and Environmental Sciences,2021,30(11):2244-2250.
[28] 陈金龙.废弃矿山生态恢复下不同植被模式的恢复效果研究[J].绿色科技，2022,24(12):222-224.CHEN J L.Study on the restoration effect of different vegetation modes under ecological restoration of abandoned mines[J].Green Technology,2022,24(12):222-224.
[29] LIU J,ZHANG S,LI E,et al.Effects of cubic ecological restoration of mining wasteland and the preferred restoration scheme[J].Science of the Total Environment,2022,851:158155.DOI:10.1016/j.scitotenv.2022.158155.
[30] 李云祯，董荐，刘姝媛，等.基于风险管控思路的土壤污染防治研究与展望[J].生态环境学报，2017,26(6):1075-1084.LI Y Z,DONG J,LIU S Y,et al.Prospect and research of soil pollution control based on risk management[J].Ecology and Environmental Sciences,2017,26(6):1075-1084.
[31] ANAMAN R,PENG C,JIANG Z,et al.Identifying sources and transport routes of heavy metals in soil with different land uses around a smelting site by GIS based PCA and PMF[J].Science of the Total Environment,2022,823:153759.DOI:10.1016/j.scitotenv.2022.153759.
[32] YE Y Y,LI Y P,CAO Z L,et al.Experimental and numerical study on Cu and Cd migration in different functional-area soils under simulated rainfall conditions[J].Environmental Research,2022,208:112239.DOI:10.1016/j.envres.2021.112239.
[33] 郑颖，赵亮，郝砚华，等.膜阻隔技术在土壤污染风险管控中应用的可行性研究[J].环境生态学，2021,3(3):60-64.ZHENG Y,ZHAO L,HAO Y H,et al.Study on applicability of technology of the membrane enclosure barrier in soil contamination risk management[J].Ecology and Environmental Sciences,2021,3(3):60-64.
[34] 臧常娟，孙玉超，刘志阳，等.原位水平阻隔风险管控技术在某退役工业污染场地治理中的应用[J/OL].环境工程技术学报：1-12[2023-06-08].http://libdb.csu.edu.cn:80/rwt/CNKI/http/NNYHGLUDN3WXTLUPMW4A/kcms/detail/11.5972.X.20221129.1650.008.html.ZANG C J,SUN Y C,LIU Z Y,et al.Application of in-situ horizontal barrier risk control technology in controlling a decommissioned industrial contaminated site[J/OL].Journal of Environmental Engineering Technology:1-12[2023-06-08].http://libdb.csu.edu.cn:80/rwt/CNKI/http/NNYHGLUDN3WXTLUPMW4A/kcms/detail/11.5972.X.20221129.1650.008.html.
[35] 王劲楠，吴玉锋，李良忠，等.场地重金属复合污染阻隔技术研究进展[J].环境工程，2022,40(4):244-253.WANG J N,WU Y F,LI L Z,et al.Research progress of heavy metal composite pollution barrier technology in site[J].Environmental Engineering,2022,40(4):244-253.
[36] ZHAO X,HUANG X,WANG Z,et al.Composite-polymer modified bentonite enhances anti-seepage and barrier performance under high-concentration heavy-metal solution[J].Journal of Cleaner Production,2022,376:134253.DOI:10.1016/j.jclepro.2022.134253.
[37] 龙涛.基于风险管控的污染地块修复模式概述[J].环境保护科学，2016,42(4):36-39.LONG T.Introduction of remediation strategies of contaminated sites based on risk management and control[J].Environmental Protection Science,2016,42(4):36-39.
[38] 马妍，史鹏飞，彭政，等.国外污染场地制度控制及对我国场地风险管控的启示[J].环境工程学报，2022,16(12):4095-4107.MA Y,SHI P F,PENG Z,et al.Institutional control for contaminated site in foreign country and enlightment for risk control of contamination site in China[J].Chinese Journal of Environmental Engineering,2022,16(12):4095-4107.
[39] 杜超，于凤娟，曾婉秋，等.离子型稀土矿区河流氨氮污染及防治对策研究[J].赣南师范大学学报，2022,43(6):101-107.DU C,YU F J,ZENG W Q,et al.Advance of ammonia nitrogen pollution and countermeasures for water environment in ionic rare earth mines[J].Journal of Gannan Normal University,2022,43(6):101-107.
[40] 党志，姚谦，陈锴，等.粤北大宝山矿区污染成因与源头控制技术应用进展[J].农业环境科学学报，2021,40(7):1377-1386.DANG Z,YAO Q,CHEN K,et al.The cause of pollution and the application progress of source control technology in Dabaoshan mining area in north Guangdong province[J].Journal of Agro-Environment Science,2021,40(7):1377-1386.
[41] 李景芬，黄伟光.韶关某铜硫矿废弃矿区土壤修复工程措施及修复效果评估[J].有色金属(矿山部分),2022,74(6):122-125,137.LI J F,HUANG W G.Soil remediation engineering measures and effect evaluation of an abandoned copper-sulfur mine in Shaoguan[J].Nonferrous Metals (Mining Section),2022,74(6):122-125,137.
[42] 张昊.矿山土地污染现状及修复技术进展[J].华北自然资源，2021(5):97-98,101.ZHANG H.Current situation of mine land pollution and progress of remediation technology[J].Huabei Natural Resources,2021(5):97-98,101.
[43] 骆永明，滕应.我国土壤污染的区域差异与分区治理修复策略[J].中国科学院院刊，2018,33(2):145-152.LUO Y M,TENG Y.Regional difference in soil pollution and strategy of soil zonal governance and remediation in China[J].Bulletin of Chinese Academy of Sciences,2018,33(2):145-152.
[44] 刘明凤，吴永贵，李晓涵，等.模拟喀斯特环境下铅锌冶炼废渣重金属释放特征及生物效应[J].环境污染与防治，2021,43(8):973-979.LIU M F,WU Y G,LI X H,et al.Release characteristics and biological effects of heavy metals from lead-zinc smelting slag in simulated karst environment[J].Environmental Pollution & Control,2021,43(8):973-979.
[45] ZHAN J,LI X,CHRISTIE P,et al.A review of soil potentially toxic element contamination in typical karst regions in southwest China[J].Current Opinion in Environmental Science & Health,2021,23:100284.DOI:10.1016/j.coesh.2021.100284.
[46] 李鑫龙，吴永贵，文吉昌，等.黔西南汞铊矿废弃物中污染物释放的联合调控研究[J].地球与环境，2021,49(5):539-550.LI X L,WU Y G,WEN J C,et al.Release characteristics and joint control of typical highly toxic pollutants in the waste of mercury-thallium mine in Southwest Guizhou[J].Earth and Environment,2021,49(5):539-550.
[47] 廖文静.云南淘金沟锡矿山地质环境问题调查与恢复治理研究[D].昆明：昆明理工大学，2021.LIAO W J.Source distribution and pollution evaluation of heavy metals in the wasteland of Taojingou tin mine,Yunnan[D].Kunming:Kunming University of Science and Technology,2021.
[48] 刘传娥，李生清，胡靖爽，等.“双碳”战略下废弃露天矿山生态修复模式研究与实践：以山东省废弃露天矿山为例[J].山东国土资源，2022,38(9):40-44.LIU C E,LI S Q,HU J S,et al.Study and practices on ecological restoration mode under the strategy of “carbon peaking and carbon neutrality goals”:taking abandoned open pit mines in Shandong province as an example[J].Shandong Land and Resources,2022,38(9):40-44.
[49] 徐峰，刘宝蕴，梁信.我国现阶段污染地块土壤风险管控体系及工程案例浅析[C]//中国环境科学学会2019年科学技术年会：环境工程技术创新与应用分论坛论文集(三).北京：《工业建筑》杂志社有限公司，2019:640-645,724.XU F,LIU B Y,LIANG X.Analysis of soil risk management and control system and cases of contaminated site in China at the present stage[C]//2019 Science and Technology Annual Conference of Chinese Society of Environmental Sciences:Proceedings of the Sub-forum on Innovation and Application of Environmental Engineering Technology (Ⅲ).Beijing:Industrial Buildings Magazine Limited Company,2019:640-645,724.
[50] 朱月琪，李国健，蔡宗平，等.暂不开发利用污染地块风险管控实例研究[J].环境科学与管理，2022,47(11):5-9,30.ZHU Y Q,LI G J,CAI Z P,et al.Risk management and control of contaminated sites temporally undeveloped[J].Environmental Science and Management,2022,47(11):5-9,30.
[51] YANG W T,CHEN Y L,YANG L Y,et al.Spatial distribution,food chain translocation,human health risks,and environmental thresholds of heavy metals in a maize cultivation field in the heart of China′s karst region[J].Journal of Soils and Sediments,2022,22(10):2654-2670.
[52] KARACA O,CAMESELLE C,REDDY K R.Mine tailing disposal sites:contamination problems,remedial options and phytocaps for sustainable remediation[J].Reviews in Environmental Science and Bio-technology,2018,17(1):205-228.
[53] LI H,YAO J,MIN N,et al.Comprehensive evaluation of metal(loid)s pollution risk and microbial activity characteristics in non-ferrous metal smelting contaminated site[J].Journal of Cleaner Production,2022,344:130999.DOI:10.1016/j.jclepro.2022.130999.
[54] LI H,YAO J,MIN N,et al.Comprehensive assessment of environmental and health risks of metal(loid)s pollution from non-ferrous metal mining and smelting activities[J].Journal of Cleaner Production,2022,375:134049.DOI:10.1016/j.jclepro.2022.134049.
[55] 柯强，冯康宏，曹心德，等.基于模糊数学的场地重金属污染风险综合评价[J].中国环境科学，2023,43(1):415-423.KE Q,FENG K H,CAO X D,et al.Comprehensive assessment method of site heavy metal pollution risk based on fuzzy mathematics[J].China Environmental Science,2023,43(1):415-423.
[56] HONG Y,LI D,XIE C,et al.Combined apatite,biochar,and organic fertilizer application for heavy metal co-contaminated soil remediation reduces heavy metal transport and alters soil microbial community structure[J].Science of the Total Environment,2022,851:158033.DOI:10.1016/j.scitotenv.2022.158033.
[57] 赵建锋.有色冶炼场地土壤中砷、锑的污染特征及淋洗药剂筛选研究[D].上海：华东理工大学，2021.ZHAO J F.Study on the pollution characteristics of arsenic and antimony in non-ferrous smelting soil and the screening of soil washing eluents[D].Shanghai:East China University of Science and Technology,2021.
基本信息:
中图分类号:X53
引用信息:
[1]阳翠红,杨志辉,司梦莹,等.基于风险管控的矿区污染修复技术与模式综述[J].有色金属(冶炼部分),2023(12):59-68.
基金信息:
国家重点研发计划项目(2021YFC1809203)
2023-11-21
2023-11-21