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结合目前国内冶金行业发展现状及环境污染问题，揭示了含氟化氢(HF)和氯化氢(HCl)废气治理与资源化利用的重要性和必要性。介绍了工业含氟、氯废气的主要来源及危害，分析了目前含氟和含氯废气单独处理的各种方法的原理及优缺点。湿法工艺因其高效、直接、操作简单的优点而广泛应用于冶炼烟气领域。然而，湿法吸收这两种气体也存在二次污染和水资源的浪费等问题。提出利用干法吸附协同净化这两种气体更经济、更环保、更高效的新思路。
Abstract：The importance and necessary of treatment and resource utilization of waste gas containing hydrogen fluoride(HF)and hydrogen chloride(HCl)were revealed by combining the current development status of domestic metallurgical industry and environmental pollution problems.The main sources as well as hazards of industrial fluorine and chlorine containing waste gases were introduced, and the principles as well as advantages and disadvantages of various current methods for separate treatment of fluorine and chlorine containing waste gases were analyzed.The wet process is widely used in the field of smelting flue gas because of its high efficiency, directness and simple operation.However, wet adsorption of these two gases also has problems such as secondary pollution and waste of water resources.A new idea is provided to synergistically purify these two gases which proposed to be more economical, environmentally friendly and efficient method by dry adsorption.
[1] 柴立元，王云燕，孙竹梅，等.绿色冶金创新发展战略研究[J].中国工程科学，2022,24(2):10-21.CHAI L Y,WANG Y Y,SUN Z M,et al.Innovative development strategy of green metallurgy[J].Strategic Study of CAE,2022,24(2):10-21.
[2] WANG C R,LIU B S,SUN F X,et al.New challenge of microporous metal-organic frameworks for adsorption of hydrogen fluoride gas[J].Materials Letters,2017,197:175-179.
[3] MCINTOSH G J,AGBENYEGAH G E K,HYLAND M M,et al.The pivotal role of alumina pore structure in HF capture and fluoride return in aluminum reduction[J].JOM,2016,68(9):2463-2471.
[4] CHENG M D.Atmospheric chemistry of hydrogen fluoride[J].Journal of Atmospheric Chemistry,2018,75(1):1-16.
[5] DAWE K E R,FURLANI T C,KOWAL S F,et al.Formation and emission of hydrogen chloride in indoor air[J].Indoor Air,2019,29(1):70-78.
[6] SOHN J S,RHO S G,SOHN J Y,et al.Efficient solid reducing agent CaO/SiO2 hybrid composite for hydrogen fluoride elimination[J].Advanced Composite Materials,2019,28(Supplement 1):65-77.
[7] KOORNNEEF J,VAN KEULEN T,FAAIJ A,et al.Life cycle assessment of a pulverized coal power plant with post-combustion capture,transport and storage of CO2[J].International Journal of Greenhouse Gas Control,2008,2(4):448-467.
[8] TSAI W T.Environmental and health risks of chlorine trifluoride(ClF3),an alternative to potent greenhouse gases in the semiconductor industry[J].Journal of Hazardous Materials,2011,190(1):1-7.
[9] HAVERKAMP R G,METSON J B,HYLAND M M,et al.Adsorption of hydrogen fluoride on alumina[J].Surface and Interface Analysis,1992,19:139-144.
[10] CAO J,CHEN T,JIN B,et al.Adsorption of HCl on calcined Ca and Zn hydrotalcite-like compounds(HTLs)at medium-high temperature in flue gas[J].Industrial & Engineering Chemistry Research,2019,58(1):18-26.
[11] LI C,HE S,JIANG D,et al.Hydrogen fluoride adsorption ability of some inorganic compounds[J].Advanced Materials Research,2011,412:1-4.
[12] AFZAL S,RAHIMI A,EHSANI M R,et al.Experimental study of hydrogen fluoride adsorption on sodium fluoride[J].Journal of Industrial and Engineering Chemistry,2010,16(1):147-151.
[13] 唐平，曹先艳，赵由才，冶金过程废气污染控制与资源化[M].北京：冶金工业出版社，2008.TANG P,CAO X Y,ZHAO Y C.Waste gas pollution control and resource recovery in metallurgical process[M].Beijing:Metallurgical Industry Press,2008.
[14] 明扬，黄羽飞.我国铜冶炼废气治理技术研究[J].农业与技术，2015,35(18):230-231.MING Y,HUANG Y F.Study on treatment technology of copper smelting waste gas in China[J].Agriculture and Technology,2015,35(18):230-231.
[15] 尉继英，张振中，江锋，等.有色金属铜镍冶炼烟气中微量氟化物的形态分析[J].清华大学学报(自然科学版),2010,50(12):1925-1929.WEI J Y,ZHANG Z Z,JIANG F,et al.Speciation analysis of the fluoride in the smelting flue gas of copper and nickel metallurgy[J].Journal of Tsinghua University(Science and Technology),2010,50(12):1925-1929.
[16] 张评，冯权莉.电解铝废气处理的研究进展[J].化工科技，2018,26(5):63-67.ZHANG P,FENG Q L.Research progress on treatment of waste gas in electrolytic aluminum industry[J].Science & Technology in Chemical Industry,2018,26(5):63-67.
[17] 李凌成.利用磷化工含氟废气制备氢氟酸[J].中文信息，2017(2):280.LI L C.Preparation of hydrofluoric acid using waste gas containing fluoride in phosphate chemical industry[J].Chinese Information,2017(2):280.
[18] 付良恩，唐秀凤，孙振海.玻纤池窑废气处理技术发展[J].玻璃纤维，2012(3):36-40.FU L E,TANG X F,SUN Z H.Progress in waste gas treatment for fiberglass furnaces[J].Fiber Glass,2012(3):36-40.
[19] 王敏.含氟废气的综合利用[J].有机氟工业，2007(2):43-47.WANG M.Comprehensive utilization of fluorine waste gas[J].Organo-Fluorine Industry,2007(2):43-47.
[20] 齐财天.氟化氢生产中的危险有害因素分析及安全对策措施[J].化工管理，2018(6):45.QI C T.Analysis of hazardous factors in hydrogen fluoride production and safety countermeasures[J].Chemical Enterprise Management.2018(6):45.
[21] LEE Y J,JEONG I B.Chemical pneumonitis by prolonged hydrogen fluoride inhalation[J].Respiratory Medicine Case Reports,2021,32:101338.DOI:10.1016/j.rmcr.2020.101338.
[22] 王晓彤，李艳萍，刘秀玲，等.急性氯化氢吸入247例临床分析[J].中国工业医学杂志，2017,30(1):26-27.WANG X T,LI Y P,LIU X L,et al.Clinical analysis on 247 cases of acute hydrogen chloride inhalation[J].Chinese Journal of Industrial Medicine,2017,30(1):26-27.
[23] 夏克立.我国磷肥生产中氟资源的利用及其经济效益[J].磷肥与复肥，2009,24(4):64-67,82.XIA K L.Elementary description of fluorine resource in phosphate fertilizer production and its economic benefits[J].Phosphate & Compound Fertilizer,2009,24(4):64-67,82.
[24] 王贺云，刘晓红，粱志鸿.磷肥副产氟硅酸综合利用概述[J].硫磷设计与粉体工程，2005(3):17-20.WANG H Y,LIU X H,LIANG Z H.Comprehensive utilization of phosphate fertilizer byproduct fluosilicic acid[J].Sulphur Phosphorus & Bulk Materials Handling Related Engineering,2005(3):17-20.
[25] 张慧芳，张冬冬，宁平，等.含氟废气的治理及资源化利用研究进展[J].磷肥与复肥，2018,33(11):29-34.ZHANG H F,ZHANG D D,NING P,et al.Research progress of treatment and utilization of waste gas containing fluorine[J].Phosphate & Compound Fertilizer,2018,33(11):29-34.
[26] 罗建志，王少波，杨献奎.氟化氢处理技术及应用研究进展[J].化工新型材料，2011(增刊1):33-36.LUO J Z,WANG S B,YANG X K.Progress in the techniques and applications of dealing with hydrogenl fluoride[J].New Chemical Materials,2011(S1):33-36.
[27] 宋瑞金，张爱军.离子交换纤维对HF气体的动态吸附研究[J].卫生研究，2002,31(5):382-384.SONG R J,ZHANG A J.Study on dynamic adsorption of HF gas by ion-exchange fiber[J].Journal of Hygiene Research,2002,31(5):382-384.
[28] 仇晓丰，吴春森，伍明霞.浅谈氯化氢吸收与盐酸脱吸技术[J].氯碱工业，2004,40(1):32-36.QIU X F,WU C S,WU M X.Brief discussion on hydrogen chloride absorption process andhydrochloric acid desorption process[J].Chlor-alkali Industry,2004,40(1):32-36.
[29] 陈德珍，林瑜，汪雄平，等.改性石灰吸收HCl气体过程中的物理化学特性[J].同济大学学报(自然科学版),2004,32(1):72-77.CHEN D Z,LIN Y,WANG X P,et al.Physical and chemical characteristics of modified limes when used as HCl dry absorbents[J].Journal of Tongji University(Nature Science),2004,32(1):72-77.
[30] 郭小汾，杨雪莲，李海滨，等.钙化合物的种类对脱氯特性的影响[J].环境科学学报，2000,20(6):776-780.GUO X F,YANG X L,LI H B,et al.The characteristic of chlorine removal by calcium[J].Acta Scientiae Circumstantiae,2000,20(6):776-780.
[31] 李锦.高浓度HCl废气的治理[J].资源节约与环保，2014(4):103-105.LI J.Treatment of high concentration HCl waste gas[J].Resources Economization & Environmental Protection,2014(4):103-105.
[32] 吴立，罗红.干法去除垃圾焚烧炉烟气中氯化氢的研究[J].铁道劳动安全卫生与环保，2002,29(5):205-208.WU L,LUO H.Study on the dry removal of HCl in flue gas in waste cinerator[J].Railway Occupational Safety,Health & Environmental Protection,2002,29(5):205-208.
[33] 王泽安.活性炭纤维协同脱除 HCl/NO/SO2的实验与机理研究[D].武汉：华中科技大学，2017.WANG Z A.Experimental and mechanism studies on combined removal of HCl/NO/SO2 using activated carbon fibers[D].Wuhan:Huazhong University of Science and Technology,2017.
[34] LEE M T,WANG Z Q,CHANG J R.Activated-carbon-supported NaOH for removal of HCl from reformer process streams[J].Industrial & Engineering Chemistry Research,2003,42(24):6166-6170.
[35] TSUBOUCHI N,MOCHIZUKI Y,SHINOHARA Y,et al.Formation of surface chlorine species by low temperature reaction of HCl with metal-doped carbon[J].Fuel,2019,246:51-59.
[36] 刘惠，孔丝纺，刘阳生，等.二氧化钛脱除高温烟气中的氯化氢[J].环境工程学报，2014,8(9):3875-3880.LIU H,KONG S F,LIU Y S,et al.Removal of HCl from high-temperature flue gas by titanium dioxide[J].Chinese Journal of Environmental Engineering,2014,8(9):3875-3880.
[37] KAMEDA T,UCHIYAMA N,PARK K S,et al.Removal of hydrogen chloride from gaseous streams using magnesium-aluminum oxide[J].Chemosphere,2008,73(5):844-847.
[38] KAMEDA T,UCHIYAMA N,YOSHIOKA T.Treatment of gaseous hydrogen chloride using Mg-Al layered double hydroxide intercalated with carbonate ion[J].Chemosphere,2010,81(5):658-662.
[39] KAMEDA T,UCHIYAMA N,YOSHIOKA T.Treatment of gaseous hydrochloric acid with magnesium-aluminum oxide using batch operation[J].Desalination,2011,280(1):424-427.
[40] KAMEDA T,TOCHINAI M,KUMAGAI S,et al.Simultaneous treatment of HCl-SO2-NOx gas with Mg-Al layered double hydroxide intercalated with CO■and its recycling process[J].International Journal of Environmental Science and Technology,2020,17(2):1179-1184.
[41] LIANG S Y,LIU S Y,FAN Z Y,et al.Enhanced HCl removal from CO2-rich mixture gases by CuOx/Na2CO3 porous sorbent at low temperature:kinetics and forecasting[J].Chemical Engineering Journal,2020,381:122738.DOI:10.1016/j.cej.2019.122738.
[42] FONSECA A M,ORFAO J J,SALCEDO R L.A new approach to the kinetic modeling of the reaction of gaseous HCl with solid lime at low temperatures[J].Chemical Engineering Science,2003,58(15):3499-3506.
[43] CHISHOLM P N,ROCHELLE G T.Dry absorption of HCl and SO2 with hydrated lime from humidified flue gas[J].Industrial & Engineering Chemistry Research,1999,38(10):4068-4080.
[44] YAN R,CHIN T,LIANG D T,et al.Kinetic study of hydrated lime reaction with HCl[J].Environmental Science & Technology,2003,37(11):2556-2562.
[45] DAL P A,MORICONE R,ANTONIONI G,et al.Hydrogen chloride removal from flue gas by low-temperature reaction with calcium hydroxide[J].Energy & Fuels,2018,32(1):747-756.
[46] SUTHERLAND-HARPER S,LIVENS F,PEARCE C,et al.Interactions of HCl and H2O with the surface of PuO2[J].Journal of Nuclear Materials,2019,518:256-264.
[47] 李玲，马清祥，赵天生.四氯乙烷脱除氯化氢反应的动力学研究[J].能源研究与管理，2011,3(4):27-30.LI L,MA Q X,ZHAO T S.Study on the kinetics of dehydrochlorination of tetrachloroethane[J].Energy Research and Management.2011,3(4):27-30.
[48] 胡春红.含不同添加金属的类水滑石吸附剂制备与脱氯性能研究[D].南京：东南大学，2016.HU C H.Dechlorination performance of three hydrotalcite-like compounds in medium-high temperature[D].Nanjing:Southeast University,2016.
[49] AKUETTEH T,DONALDSON A A.Limestone′s performance as a solid adsorbent for HF and HCl generated in refrigerant destruction applications[J].Korean Journal of Chemical Engineering,2014,31(10):1885-1891.
[50] FENG J,LI K,NING P,et al.Preparation of MgX/Al2O3-Y sorbent for highly efficient simultaneous removal of hydrogen fluoride and hydrogen chloride under low-temperature environment[J].Environmental Technology,2022:2026484.DOI:10.1080/09593330.2022.2026484.
基本信息:
中图分类号:X758
引用信息:
[1]高鹏,伍海霞,李凯,等.冶炼烟气中氟化氢和氯化氢气体脱除的研究现状与展望[J].有色金属(冶炼部分),2023(01):18-24.
基金信息:
国家自然科学基金资助项目(52260013)
2022-12-27
2022-12-27